The overall properties of the composite were the best when the content of - nucleating agent was 0 . 5 % and the content of aid crosslinking agent was 3 % , the property of the composite came close to that of common engineering plastics 当成核剂用量为0 . 5 % 、助交联剂为3 %时,复合材料的综合性能达到最好,接近普通工程塑料的各项力学性能。
The results from x - ray diffraction demonstrated that pp / mmtome was a fully intercalated nanocomposite , pp / mmtom and pp / ommt were partly intercalated nanocomposites , but the intercalation effect of pp / mmtom nanocomposite was better ; the crystallization characteristics of pure pp and pp / mmt nanocomposites were investigated by dsc , waxd and pom . the result of these testing showed that mmt nano - layers acted as nucleating agents for the crystallization of pp , the addition of mmt had effect on the crystallization process , leading the increasing of crystallization temperature crystallization rate and crystallinity , but also the dimension of spherulite reduced . but the formation of pp crystal did n ' t change , the formation of pp crystal in three pp / mmt nanocomposites and pure pp were a - form on the whole ; influences of three sorts of mmt on mechanical properties of pp / mmt nanocomposites were studied , as a result , the addition of mmt comprehensively improved mechanical properties of pp : notched impact strength , tensile strength and flexural properties were all increasing , but the extent of increasing were n ' t large 通过xrd分析比较这三种pp mmt纳米复合材料微观结构得到, pp mmt _ ( ome )属于完全插层, pp mmt _ ( om )与pp ommt的插层程度相近,但是pp mmt _ ( om )相对较好;通过对纯pp和三种pp mmt纳米复合材料的结晶性能研究发现,蒙脱土纳米片层对pp结晶产生明显的异相成核作用,结晶能力增强,使pp的结晶温度和结晶速率提高,结晶度增加,球晶晶粒细化,但是没有改变pp的结晶形态,三种pp mmt纳米复合材料的结晶形态都属于晶;通过对pp mmt纳米复合材料的力学性能测试得知,蒙脱土的加入全面提高了pp的力学性能,缺口冲击强度、拉伸强度和弯曲性能都有一定程度的提高,浙江{ _业大学硕十学位论文摘要但是提高幅度都不是很大,不过ommt 、 mmtom和mmtc ) me三种蒙脱土对pp力学性能有着不同的改性作用,其中pp / mmtom最好, pp月边mto崛次之, pp / ommt最低,这种情况主要是由蒙脱土对pp结晶性能的影响和蒙脱土的纳米改性作用造成的。
Their properties have been investigated by using scanning electronic microscopy ( sem ) , differential scanning calorimetry ( dsc ) , x - ray diffraction ( xrd ) , thermogravimetry - differential thermal analysis ( tg - dta ) , infrared spectroscopic analysis ( ir ) , and gas chromatography ( gc ) , etc . the effects of the mulser ' s stirring rate and the emulsifier concentration on the properties of encapsulated pcms have been systematically studied , and nanopcms have been obtained by increasing the stirring rate or the emulsifier concentration . the influences of different nucleating agents on micropcm performances have also been investigated in detail to search for a suitable nucleating agent to prevent micropcms from super - cooling 首先,系统研究了乳化机转速和乳化剂浓度对胶囊性能的影响,并通过提高转速或乳化剂浓度获得相变材料纳胶囊;其次,系统研究了不同成核剂对微胶囊性能的影响,找到合适的成核剂抑制了相变材料微胶囊的过冷现象;再次,详细研究了环己烷对胶囊性能的影响,并通过添加适量环己烷提高了相变材料微胶囊及纳胶囊的耐热温度。
With the addition of nucleating agent , the crystallinity increased , resulted in higher rigidity and lower impact strength than those of pure pp ; while with the addition of - nucleating agent , the relative content of crystalline form of special sheaf - like structure increased and resulted in increase of impact strength and the toughness 成核剂的加入使聚丙烯结晶度增大,从而使刚性增加,但抗冲击强度有所下降;成核剂的加入使聚丙烯中晶含量大幅度地提高,从而使聚丙烯抗冲击强度提高,即韧性增加。
On the basis of survering of the relative literature , the mechanism and the present application of nanocomposite technologies in toughening and reinforcing pvc are detailedly introduced in this paper . it is inferred that fine pvc and nanometer caco3 / pvc mixture are used to toughen and reinforce pvc . in this paper , the crystallinity of pvc modified by homemade nucleating agent is increased 在查阅大量国内外有关纳米复合技术增韧增强聚氯乙烯( pvc )文献资料的基础上,本文对纳米复合技术增韧增强pvc的作用机理和研究现状进行了总结,提出了用pvc微粉和纳米caco _ 3 pvc母料对pvc进行增韧增强改性的设想。
This has an important meaning to the industrial manufacture . dsc , waxd and polarizing microscope with hot stage experiments were performed to describe what led the ssp rate acceleration of pet / mmt . it was shown that montmorillonite acted as a very good nucleating agent in pet crystallization process , which results in the lower crystallinity , more small microlites , and more surfaces of microlites 为研究pet mmt固相缩聚效率提高的原因,通过热台偏光显微镜、 dsc 、 x -射线衍射等手段对样品的结晶进行观察与分析研究,结果表明蒙脱土对pet的结晶有明显的成核作用,使其晶核生成速率迅速提高,晶核数量明显增多,从而使整个结晶过程的时间变短,同时形成了更多结构不完善的微晶体。