From a viewpoint of organic synthesis chemistry , the recent development and applications of molecular iodine as a catalyst in organic reactions including the formation and cleavage of common protecting groups , oxidation , reduction , cyclization , addition , substitution and rearrangement are reviewed 从有机合成化学的角度,按反应类型综述了分子碘作为催化剂在有机化学中的应用,碘催化的反应主要涉及保护基团的形成和裂解、氧化和还原反应、成环反应、加成反应、取代反应和重排反应等。
From a viewpoint of organic synthesis chemistry , the recent development and applications of molecular iodine as a catalyst in organic reactions including the formation and cleavage of common protecting groups , oxidation , reduction , cyclization , addition , substitution and rearrangement are reviewed 摘要从有机合成化学的角度,按反应类型综述了分子碘作为催化剂在有机化学中的应用,碘催化的反应主要涉及保护基团的形成和裂解、氧化和还原反应、成环反应、加成反应、取代反应和重排反应等。
Hydroxyquinol triacetate was prepared from p - benzoquinone by 1 , 4 - addition reaction with acetic anhydride and then 6 , 7 - dihydroxy coumarin was synthesized from it by hydrolyze and cyclization in concentrated sulfuric acid . then 6 , 7 - dimethoxy coumarin was synthesized by methylating from 6 , 7 - dihydroxy coumarin with an overall yield of 74 . 4 % . the procedure was practical . its structure was confirmed by ir and 1hnmr 对苯醌与乙酸酐经1 , 4 -加成生成1 , 2 , 4 -苯三酚三乙酸酯,然后与苹果酸反应经水解、环合反应得6 , 7 -二羟基香豆素,再经甲基化得到6 , 7 -二甲氧基香豆素,总收率为74 . 4 % ,整个过程反应条件温和,操作方便,适合工业生产的要求,对产品结构进行了ir和1hnmr表征。
cyclizationとは意味:cyclization 環化 かんか cyclization meaning:[Medicine] Changing an open-chain hydrocarbon to a closed ring. (McGraw-Hill Dictionary of Scientific and Technical Terms,5th ed) or Brit cy·cli·sa·tion n : formation of one or more rings in a ...cyclization 뜻:고리화cyclization перевод:1) _хим. образование, замыкание кольца, циклизация